Well hopefully when Oprah is discontinued next year, they can put Millionaire at 4pm.
I remember during the first season Millionaire went into syndication, KYW 3 aired the show instead, at I think 4pm, which was a MUCH better timeslot. Then WPVI acquired the rights after ABC's soap opera Port Charles (which aired at 12:30) ended in 2003. Around that same time was when KYW did away with the afternoon game show block, moved their 5pm newscast to 4, and aired Dr. Phil at 5.